He is not abusing her in anyway that the good folks here in the dumbest state would care about.. I was friends with a social worker and she had to get out of it because she couldn't take it anymore. They wouldn't remove kids..
Option #1 - Honey - You could call your ex-H and tell him you miss D14, so it would mean the world to you if he dropped D14 off when he left overnight. I recall many times while you maintained NC, Ex-H tried to do nice things for you. Guilt? I get you hate the idea of interacting with him, but it's for D14, not for you.
Option #2 - Vinegar - You could call Child Protective Services. I agree, they prefer correction to removal. The outcome may be no problem found or maybe they disallow him from leaving her home alone overnight. You don't need to predict the outcome. You simply file a claim and let them figure it out.
Personally, I suspect HONEY will do more for you than VINEGAR, but these are two options.
(Beyond, of course, asking a judge for 50% custody of D14.)