She's married? Currently? Or her exH?

If she's currently married and living with her H, you might consider clueing him in. This is fraught with issues - your H will hate you for it, he might be a bad man who would endanger the affair partner or her children etc. But on the other hand - I FIRMLY believe everyone has the right to know when their partner is cheating on them. If he doesn't know he deserves to be told.